Dreaded Orange Spots (DOS), Rancid Soap and What To Do.
Thursday, November 6th, 2008The Dreaded Orange Spots (DOS) happen when extra oils or free fatty acids in handcrafted soaps go rancid or oxidize. They usually happen on soap that has been over superfatted, however they can appear on soaps containing very little extra oils. It’s really sad when this happens, the soaps are not so pretty, and sometimes they smell a bit rancid too. But the soaps are perfectly good to use, they just don’t look so hot.
If your soap has small orange spots on the surface of it and you have not added anything orange to your soap, chances are you have developed DOS, the dreaded orange spots, rancidity. What causes these DOS to appear?
Heat and light and moisture and oxygen all can play a part in the process, but rancidity is basically oxidation of the free fatty acids in the soap. Storing your soap and a warm humid area will exacerbate the problem and speed up the process tremendously. If you intend to store your soaps for any length of time, a cool, dry, dark place is idea. Using a corrugated cardboard box will also help when storing soap. It won’t trap moisture like a plastic container, corrugated cardboard insulates well, and also will help keep the soap dry by absorbing what moisture may be present inside the box.
Adding antioxidants to your soaps should help stop the oxidation. There are many things that can be added to your soap to help slow down the process. Adding tocopherols or vitamin E which has antioxidant properties will help. If you don’t mind yellow soap, or even if you want yellow soap, you can beta carotene which is vitamin and also an antioxidant. There’s also lycopene which is a powerful antioxidant. Lycopene is from tomatoes, red fruits and veggies, etcetera and like beta carotene may be pigmented so it may or may not color the soap. A few more additives to help in stopping or slowing down DOS and rancidity are Selenium and Co Q-10. Take a look at your local vitamin or health food store, they’ll have tons of antioxidants.
There’s also grapefruit seed extract (GSE) and rosemary oleoresin or rosemary oil extract (ROE) which are also good antioxidants, but last time I checked they were kind of expensive for soaping. GSE may speed up trace time in soaps.
Also, using oils that have BHT or BHA or whatever it is they put in vegetable oil at the grocery store seems to help with the rancidity problems. But then you have the question of “Do you want that in your soap?” and “Do you care since it is a rinse off product?”. Many people don’t mind, but some people have very strong opinions about BHT and BHA and may not like it in their soaps. It really just depends on your marketing niche. BHT or BHA or whatever is also available at the health food store.